@MayAnnTenorio I would start by testing that you have the right target application by using MonitorAll as the StartMethod and setting the Path equal to the application you are interested in. Click Start Interrogation and then manually launch the application. If you are able to interrogate it, then there must be something missing from your earlier tests.
You can also use a tool like Process Explorer to identify the exe to make sure you have the right one. If possible, take a screenshot of the process in Process Explorer and attach here and I can see if there is anything obvious you might be missing since it looks like you've been pretty thorough.
@MayAnnTenorio Would you right-click on that process and select Properties and attach that? You may blur out anything proprietary. I am most interested in the command line.
Also, would you confirm that when you attempted using MonitorAll, that the Path property was set to "RiskkOnePortfolio.exe"? Was the application not running when you started interrogation? If not, please make these changes and then let me know. To clarify;
The Path should be set to RiskkOnePortfolio.exe
The application should not be running when you start interrogation. After you start interrogation, you should launch the application.